No. The marriage of two Protestants in a Protestant Church is valid before God, and nothing can dissolve that marriage except the death of one of the parties. Divorce does not give even such Protestants the right to marry again whilst both parties are still living. And becoming a Catholic has no effect upon the validity of such a marriage.
Radio Replies Volume 1 by Rev. Dr. Leslie Rumble MSC and Rev. Charles Mortimer Carty
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The Case for Catholicism - Answers to Classic and Contemporary Protestant Objections
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The Case for Catholicism - Answers to Classic and Contemporary Protestant Objections
Disclaimer: As an Amazon Associate, I earn from qualifying purchases. Thank you.